The art for the design of a class of modified catalysts, the process for preparing such modified catalysts and implementation of such modified catalysts in phosphoric acid fuel cells is disclosed. The modified catalyst comprises a particle of a metal-doped porous material and an amount of a phosphate-containing acid group or phosphate-containing acid groups. The particle of the metal-doped porous material is a particle of a porous carrier with metal microparticles and a plurality of hydroxyl groups on the surface of the porous carrier such that (i) the plurality of metal microparticles are attached to a first portion of the plurality of hydroxyl groups of the surface of the porous carrier and (ii) an amount of a phosphate-containing acid group or phosphate-containing acid groups can be bonded to a second portion of the plurality of hydroxyl groups of the surface of the porous carrier to form the modified catalyst. |