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專利授權區

專利授權區
專利名稱(中)	製備官能基化環化合物的方法和反應混合物
專利名稱(英)	METHOD AND MIXTURE TO FORM FUNCTIONALIZED CYCLIC COMPOUNDS
專利家族	美國：US11,697,634B2
專利權人	國立清華大學 100.00%
發明人	舒曼,韓建中
技術領域	材料化工,生化醫藥

專利摘要(中)
一種製備碳環化合物或雜環化合物的方法，包括使式(I)化合物和式(II)化合物在鹼存在下反應。 R1-B-G (I) 在式(I)中，B是選自經取代或未經取代的亞乙烯基、亞乙炔基、亞芳基亞乙炔基、經取代或未經取代的亞芳基亞乙烯基及其組合的不飽和基團，所述亞乙烯基或亞芳基亞乙烯基具有n個取代基R2（n=0、1或2），G是拉電子基，R1是氫或取代基，且R1、R2和G中的兩個可以接合在一起形成環。在式(II)中，R3和R4獨立為氫或取代基，R5是拉電子基，且R3、R4和R5中的兩個可以接合在一起形成環。鹼的共軛酸的pKa在1至15的範圍內。

專利摘要(中)

一種製備碳環化合物或雜環化合物的方法，包括使式(I)化合物和式(II)化合物在鹼存在下反應。 R1-B-G (I) 在式(I)中，B是選自經取代或未經取代的亞乙烯基、亞乙炔基、亞芳基亞乙炔基、經取代或未經取代的亞芳基亞乙烯基及其組合的不飽和基團，所述亞乙烯基或亞芳基亞乙烯基具有n個取代基R2（n=0、1或2），G是拉電子基，R1是氫或取代基，且R1、R2和G中的兩個可以接合在一起形成環。在式(II)中，R3和R4獨立為氫或取代基，R5是拉電子基，且R3、R4和R5中的兩個可以接合在一起形成環。鹼的共軛酸的pKa在1至15的範圍內。

專利摘要(英)
A method for producing a homocyclic or heterocyclic compound includes reacting a compound of formula (I) with a compound of formula (II) in presence of a base: R1-B-G (I) . In formula (I), B is an unsaturated moiety selected from substituted or unsubstituted vinylene, ethynylene, aryleneethynylene, substituted or unsubstituted arylenevinylene, and a combination thereof, the vinylene or arylenevinylene has n (=0, 1 or 2) substituent(s) R2, G is an electron-withdrawing group, R1 is hydrogen or a substituent, and two of R1, R2 and G may joint together to form a ring. In formula (II), R3 and R4 are independently hydrogen or a substituent, R5 is an electron-withdrawing group, and two of R3, R4 and R5 may joint together to form a ring. The conjugate acid of the base has a pKa in the range of 1 to 15.

專利摘要(英)

A method for producing a homocyclic or heterocyclic compound includes reacting a compound of formula (I) with a compound of formula (II) in presence of a base: R1-B-G (I) . In formula (I), B is an unsaturated moiety selected from substituted or unsubstituted vinylene, ethynylene, aryleneethynylene, substituted or unsubstituted arylenevinylene, and a combination thereof, the vinylene or arylenevinylene has n (=0, 1 or 2) substituent(s) R2, G is an electron-withdrawing group, R1 is hydrogen or a substituent, and two of R1, R2 and G may joint together to form a ring. In formula (II), R3 and R4 are independently hydrogen or a substituent, R5 is an electron-withdrawing group, and two of R3, R4 and R5 may joint together to form a ring. The conjugate acid of the base has a pKa in the range of 1 to 15.

聯絡資訊
承辦人姓名	李馥如