An AgSbS2 nanowire used as anode materials and a manufacturing method thereof are disclosed. The manufacturing method includes a step (a) of dissolving a surfactant in ethylene glycol with stirring at room temperature to obtain a mixing solution; a step (b) of simultaneously adding silver nitrate, antimony chloride, and thioacetamide in the mixing solution containing the surfactant, and continuously stirring the mixing solution until an intermediate product is produced; a step (c) of transferring the mixing solution containing the intermediate product to a hydrothermal synthesis reactor, wherein the mixing solution reacts and cools in the hydrothermal synthesis reactor to form a precipitate; and a step (d) of centrifuging the mixing solution to collect the precipitate and washing the precipitate with ethanol to obtain the AgSbS2 nanowire. The AgSbS2 nanowire can be used to manufacture anode materials of batteries. |