|A manufacturing method of a high thermal conductive hybrid film includes steps as follows. A graphene oxide solution including a plurality of graphene oxides is prepared. A nano-particle solution including a plurality of nano initial hybrid structures is prepared. A mixing process is provided, wherein the mixing process is for mixing the graphene oxide solution and the nano-particle solution to obtain a mixing solution. A preliminary-film forming process is provided, wherein the preliminary-film forming process is for filtrating the mixing solution and then remaining a mixture of the graphene oxides and the nano initial hybrid structures to form a preliminary film. A heating process is provided, wherein the heating process is for heating the preliminary-film to reduce the graphene oxides as a plurality of reduced graphene oxides and convert the nano initial hybrid structures into a plurality of nano hybrid structures.